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Abstract Despite recent rapid advances in metal halide perovskites for use in optoelectronics, the fundamental understanding of the electrical‐poling‐induced ion migration, accounting for many unusual attributes and thus performance in perovskite‐based devices, remain comparatively elusive. Herein, the electrical‐poling‐promoted polarization potential is reported for rendering hybrid organic–inorganic perovskite photodetectors with high photocurrent and fast response time, displaying a tenfold enhancement in the photocurrent and a twofold decrease in the response time after an external electric field poling. First, a robust meniscus‐assisted solution‐printing strategy is employed to facilitate the oriented perovskite crystals over a large area. Subsequently, the electrical poling invokes the ion migration within perovskite crystals, thus inducing a polarization potential, as substantiated by the surface potential change assessed by Kelvin probe force microscopy. Such electrical‐poling‐induced polarization potential is responsible for the markedly enhanced photocurrent and largely shortened response time. This work presents new insights into the electrical‐poling‐triggered ion migration and, in turn, polarization potential as well as into the implication of the latter for optoelectronic devices with greater performance. As such, the utilization of ion‐migration‐produced polarization potential may represent an important endeavor toward a wide range of high‐performance perovskite‐based photodetectors, solar cells, transistors, scintillators, etc. 

Abstract Increasing performance demand associated with the short lifetime of consumer electronics has triggered fast growth in electronic waste, leading to serious ecological challenges worldwide. Herein, a robust strategy for judiciously constructing flexible perovskite solar cells (PSCs) that can be conveniently biodegraded is reported. The key to this strategy is to capitalize on meniscus‐assisted solution printing (MASP) as a facile means of yielding cross‐aligned silver nanowires in one‐step, which are subsequently impregnated in a biodegradable elastomeric polyester. Intriguingly, the as‐crafted hybrid biodegradable electrode greatly constrains the solvent evaporation of the perovskite precursor solution, thereby generating fewer nuclei and in turn resulting in the deposition of a large‐grained dense perovskite film that exhibits excellent optoelectronic properties with a power conversion efficiency of 17.51% in PSCs. More importantly, the hybrid biodegradable electrode‐based devices also manifest impressive robustness against mechanical deformation and can be thoroughly biodegraded after use. These results signify the great potential of MASP for controllably assembling aligned conductive nanomaterials for biodegradable electrodes. As such, it represents an important endeavor toward environmentally friendly, multifunctional and flexible electronic, optoelectronic, photonic, and sensory materials and devices. 

Abstract Electrohydrodynamic jet (e‐jet) printing is a high‐resolution printed electronics technique that uses an electric field to generate droplets. It has great application potential with the rapid development of flexible and wearable electronics. Triboelectric nanogenerators (TENG), which can convert mechanical motions into electricity, have found many high‐voltage applications with unique merits of portability, controllability, safety, and cost‐effectiveness. In this work, the application of a TENG is extended to printed electronics by employing it to drive e‐jet printing. A rotary freestanding TENG is applied as the high‐voltage power source for generating stable ink droplet ejection. The TENG‐driven droplet generation and ejection process and printed features with varied operation parameters are investigated. Results reveal that the jetting frequency could be controlled by the TENG's operation frequency, and high‐resolution printing with feature size smaller than nozzle size is achieved using the setup. Notably, TENG as the power source for e‐jet printing supplies a limited amount of current, which leads to better safety for both equipment and personnel compared to conventional high‐voltage power supplies. With the superiority of TENG in the sense of safety and cost, the work presents a promising solution for the next‐generation of high‐resolution printed electronics and broadens the scope of TENG application.